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Electrochemistry · E° · Nernst · concentration cells

Electrochemical cell & Nernst equation calculator

Compute standard cell potentials E°, standard ΔG°, equilibrium constants K, Nernst equation E under non-standard conditions, and concentration cell voltages with clear steps and shareable URLs.

All calculations run in your browser only; no data is sent to a server.

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How to use (3 steps)

  1. Choose a mode: standard cell, Nernst equation, or concentration cell.
  2. Enter standard potentials, electron count n, temperature (K), and concentrations or Q as needed.
  3. Compute to see E°, ΔG°, K, E under non-standard conditions, and the calculation log. Copy the URL to share.

A default Zn|Zn²⁺ || Cu²⁺|Cu example is prefilled. Press Compute to generate cell voltage, ΔG°, K, and the calculation log.

Inputs

Pick a mode, adjust the example values, then compute or copy the URL. Units use volts and mol/L for clarity.

The standard cell mode assumes standard conditions at 25 °C (about 298 K). For other temperatures or non-standard concentrations, use the Nernst equation or concentration cell modes.

Enter the more concentrated half-cell in the first box and the more dilute half-cell in the second. Swapping them flips the sign of E.

Results

Mode: Standard cell (E°, ΔG°, K)

How it's calculated

  1. Run the calculation to list the Nernst substitutions and checks.

Use this page after the redox reaction is already balanced

This calculator is for turning a known balanced cell reaction into E, ΔG, K, or Nernst-equation outputs. Open Chemical Equilibrium ICE Table for equilibrium concentration work, use Chemical Equation Balancer before you choose n, and switch to Stoichiometry & Limiting Reactant when yield or reagent ratios are the actual question.

FAQ

Do I need to balance the overall redox equation?

This tool assumes you have already combined and balanced the half-reactions, so the electron count n you enter matches the balanced overall cell reaction. It does not balance redox equations for you, but it does show how E°, ΔG°, K and the Nernst equation relate once n is known.

When should I use the concentration cell mode instead of the general Nernst mode?

Use the concentration cell mode when both half-cells are the same metal/ion pair and only the ion concentration differs. For more complicated cells (different half-reactions on each side), use the general Nernst mode and compute Q from the balanced reaction stoichiometry.

Which Nernst mode should I choose?

Use standard cell mode when all species are at standard conditions, Nernst mode when you know the reaction quotient Q, and concentration cell mode when the same redox pair appears on both sides with different ion concentrations.

How should I define the reaction quotient Q?

Build Q from the balanced overall cell reaction using product activities over reactant activities, each raised to its stoichiometric coefficient. Leave pure solids and liquids out of Q.

What does temperature change in the calculation?

Temperature changes the RT/nF term in the Nernst equation, so the same Q can shift the non-standard cell potential more or less strongly as T changes.

When is the standard potential E° enough?

E° is enough for standard-state comparisons and for deriving ΔG° or K. Use the Nernst equation when concentrations, pressures, or temperature differ from the standard assumptions.

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