How to use (3 steps)
- Choose a mode: standard cell, Nernst equation, or concentration cell.
- Enter standard potentials, electron count n, temperature (K), and concentrations or Q as needed.
- Compute to see E°, ΔG°, K, E under non-standard conditions, and the calculation log. Copy the URL to share.
A default Zn|Zn²⁺ || Cu²⁺|Cu example is prefilled. Press Compute to generate cell voltage, ΔG°, K, and the calculation log.
Results
Mode: Standard cell (E°, ΔG°, K)
How it's calculated
- Run the calculation to list the Nernst substitutions and checks.
Use this page after the redox reaction is already balanced
This calculator is for turning a known balanced cell reaction into E, ΔG, K, or Nernst-equation outputs. Open Chemical Equilibrium ICE Table for equilibrium concentration work, use Chemical Equation Balancer before you choose n, and switch to Stoichiometry & Limiting Reactant when yield or reagent ratios are the actual question.
- Confirm the overall balanced reaction and electron count before entering values.
- Choose standard, Nernst, or concentration-cell mode based on the physical setup.
- Keep temperature and quotient assumptions aligned when comparing runs.
FAQ
Do I need to balance the overall redox equation?
This tool assumes you have already combined and balanced the half-reactions, so the electron count n you enter matches the balanced overall cell reaction. It does not balance redox equations for you, but it does show how E°, ΔG°, K and the Nernst equation relate once n is known.
When should I use the concentration cell mode instead of the general Nernst mode?
Use the concentration cell mode when both half-cells are the same metal/ion pair and only the ion concentration differs. For more complicated cells (different half-reactions on each side), use the general Nernst mode and compute Q from the balanced reaction stoichiometry.
Which Nernst mode should I choose?
Use standard cell mode when all species are at standard conditions, Nernst mode when you know the reaction quotient Q, and concentration cell mode when the same redox pair appears on both sides with different ion concentrations.
How should I define the reaction quotient Q?
Build Q from the balanced overall cell reaction using product activities over reactant activities, each raised to its stoichiometric coefficient. Leave pure solids and liquids out of Q.
What does temperature change in the calculation?
Temperature changes the RT/nF term in the Nernst equation, so the same Q can shift the non-standard cell potential more or less strongly as T changes.
When is the standard potential E° enough?
E° is enough for standard-state comparisons and for deriving ΔG° or K. Use the Nernst equation when concentrations, pressures, or temperature differ from the standard assumptions.
Related calculators
- Chemical equilibrium ICE tableSet up Kc or Kp tables and compare equilibrium shifts with the same reaction-direction logic used in the Nernst mode.
- Chemical Equation Balancer + StoichiometryBalance the overall reaction before choosing the electron count n and building the reaction quotient Q.
- Stoichiometry & limiting reactantTranslate balanced coefficients into mole ratios when the electrochemical setup is part of a larger reaction worksheet.
- Beer-Lambert law & calibration curveUse this when your electrochemistry workflow also needs concentration estimates from absorbance data.
Comments
Click to load the discussion. Comments are powered by Giscus and load only when requested.